Bulk (Y, Gd)Ba2Cu3O7-𝛅 single-grain superconductors growth by the addition of sharp-edged Gd2BaCuO5 particles

Dec. 1 15:30-15:45

Rikako Hagiwara1, Natsuki Asano1, Pavan Kumar Naik Sugali1,2, Hiraku Ogino1,2, Shigeyuki Ishida2, Koblischka-Veneva Anjela3, Koblischka Michael R.3, Kenji Kawashima2,4, Hiroshi Eisaki2, Taichiro Nishio1
Department of Physics, Tokyo University of Science, 1 Chome-3 Kagurazaka, Shinjuku City, Tokyo, 162-8601, Japan1
Research Institute for Advanced Electronics and Photonics, National Institute of Advanced Industrial Science and Technology (AIST), 1-1-1 Central 2 Umezono Tsukuba, Ibaraki, 305-8568, Japan2
Experimental Physics, Saarland University, P.O. Box 151150, D-66041 Saarbrücken, Germany3
IMRA JAPAN CO., LTD., Kariya, Aichi 448-8650, Japan4

REBa2Cu3O7-δ (REBCO/RE123, RE = rare earth elements) superconductors have a wide range of applications due to their high superconducting transition temperature (Tc) of ~92 K and excellent field trapping capabilities. This is very important for developing next-generation high-magnetic field applications, which depends on the magnitude of critical current density (Jc) and how well the magnetic flux motion due to the Lorentz force is suppressed. This can be achieved by dispersing pins such as RE2BaCuO5 (RE211) particles or other nanometer-sized defects in the superconducting RE123 matrix. Recently, we have demonstrated that high-energy ultrasound irradiation effectively controls the initial RE211 (RE211Ultra) particle size. By employing the RE211Ultra particles, the Jc and trapped fields of various REBCO single-grain bulk superconductors were improved.

In this study, for improving the 123-matrix pinning, (Y1-x, Gdx)Ba2Cu3O7-d (YGdBCO) superconductors were synthesized via top-seeded melt growth method by the addition of 20 mol% of ultrasonically pre-treated (with 450 W for 30 min) Gd211 particles. Systematic isothermal experiments were conducted at various constant temperatures (from 1020 oC – 990 oC) indicating that a safe growth window for fabricating large YGdBCO bulk single grains is 1015 oC – 990 oC. The microstructural and composition studies (mapping, line scan and point scans) performed via electron microscopy and energy dispersive spectroscopy on YGdBCO samples indicated that the inclusion of the Y211 phases wrapped in Gd211 particles. All YGdBCO samples exhibited superconductivity above 92.5 K. A maximum of 74.1 kA/cm2 at 77 K and self-field was achieved in the YGdBCO sample grown at 1000 oC. Further, we will outline the relation of the developed microstructure and superconducting properties dependence on the isothermal growth temperature.

Keywords: (Y, Gd)Ba2Cu3O7-𝛅, single-grain, ultra sonication, microstructure